Sulfonamide, Phenolate, and Directing Ligand-Free Indium Initiators for the Ring-Opening Polymerization of rac-Lactide
Reaction of In(CH2SiMe3)3 with H 2N2TsNpy or H2N 2TsNOMe gave the five-coordinate indium alkyls In(N2TsNpy)(CH2SiMe3) (14) and In(N2TsNOMe)(CH2SiMe 3) (15). The corresponding reaction with H2N 2TsNPh gave four-coordinate In(N 2TsNPh)(CH2SiMe3) (16). Reaction of H2N2TsNpy with In{N(SiMe3)2}3 gave the...
| Main Authors: | , , |
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| Format: | Journal article |
| Language: | English |
| Published: |
2011
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