Diffuse Double Layer at Nanoelectrodes
Numerical solution of the equilibrium Poisson-Boltzmann equation for hemispherical electrodes of vanishing size reveals that the effects of curvature on the diffuse double layer become significant for electrodes with radii less than 50 nm. These effects include dramatically enhanced capacitance and...
| Main Authors: | , |
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| Format: | Journal article |
| Language: | English |
| Published: |
2009
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