Diastereoselective ring-closing metathesis: synthesis of P-stereogenic phosphinates from prochiral phosphinic acid derivatives.

[reaction: see text] The preparation of phosphorus-containing trienes featuring two diastereotopic vinyl moieties followed by a diastereoselective ring-closing metathesis is described. This methodology allowed for the synthesis of novel highly functionalized P-stereogenic heterocycles featuring both...

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Những tác giả chính: Dunne, K, Bisaro, F, Odell, B, Paris, J, Gouverneur, V
Định dạng: Journal article
Ngôn ngữ:English
Được phát hành: 2005