Diastereoselective ring-closing metathesis: synthesis of P-stereogenic phosphinates from prochiral phosphinic acid derivatives.

[reaction: see text] The preparation of phosphorus-containing trienes featuring two diastereotopic vinyl moieties followed by a diastereoselective ring-closing metathesis is described. This methodology allowed for the synthesis of novel highly functionalized P-stereogenic heterocycles featuring both...

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書目詳細資料
Main Authors: Dunne, K, Bisaro, F, Odell, B, Paris, J, Gouverneur, V
格式: Journal article
語言:English
出版: 2005