Analytical expressions for transient diffusion layer thicknesses at non uniformly accessible electrodes

Analytical expressions for transient diffusion layer thicknesses at non uniformly accessible electrodes

Explicit analytical expressions for the diffusion layer thicknesses of disk and band electrodes of any size, under transient conditions have been deduced. We have applied these expressions to constant potential chronoamperometry and Linear Sweep Voltammetry (LSV). The analysis of the diffusion layer...

पूर्ण विवरण

ग्रंथसूची विवरण
मुख्य लेखकों:	Molina, A, Gonzalez, J, Henstridge, M, Compton, R
स्वरूप:	Journal article
भाषा:	English
प्रकाशित:	2011

समान संसाधन

On the meaning of the diffusion layer thickness for slow electrode reactions.
द्वारा: Molina, A, और अन्य
प्रकाशित: (2013)

Geometrical Insights of Transient Diffusion Layers
द्वारा: Molina, A, और अन्य
प्रकाशित: (2010)

The transient and stationary behaviour of first-order catalytic mechanisms at disc and hemisphere electrodes
द्वारा: Molina, A, और अन्य
प्रकाशित: (2011)

Voltammetry of Electrochemically Reversible Systems at Electrodes of Any Geometry: A General, Explicit Analytical Characterization
द्वारा: Molina, A, और अन्य
प्रकाशित: (2011)

Chronoamperometry at channel electrodes: Analytical theory of transient behaviour at double electrodes
द्वारा: Compton, R, और अन्य
प्रकाशित: (1996)

Effects of convergent diffusion and charge transfer kinetics on the diffusion layer thickness of spherical micro- and nanoelectrodes.
द्वारा: Molina, A, और अन्य
प्रकाशित: (2013)

The theory of square wave voltammetry at uniformly accessible hydrodynamic electrodes
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प्रकाशित: (2000)

Marcus-Hush-Chidsey theory of electron transfer to and from species bound at a non-uniform electrode surface: Theory and experiment
द्वारा: Henstridge, M, और अन्य
प्रकाशित: (2011)

Investigation of the optimal transient times for chronoamperometric analysis of diffusion coefficients and concentrations in non-aqueous solvents and ionic liquids
द्वारा: Xiong, L, और अन्य
प्रकाशित: (2012)

Analytical theoretical approach to the transient and steady state voltammetric response of reaction mechanisms. Linear diffusion and reaction layers at micro- and submicroelectrodes of arbitrary geometry
द्वारा: Molina, A, और अन्य
प्रकाशित: (2016)

Analytical approach to the transient and steady-state Cyclic Voltammetry of non-reversible electrode processes. Defining the transition from macro to microelectrodes
द्वारा: Gonzalez, J, और अन्य
प्रकाशित: (2016)

Are steady state diffusion layer thicknesses potential independent?
द्वारा: Streeter, I, और अन्य
प्रकाशित: (2008)

Steady state voltammetry at non-uniformly accessible electrodes: a study of Tafel plots for microdisc and tubular flow electrodes in the reversible and irreversible limits of electron transfer.
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प्रकाशित: (2007)

On the estimation of the diffuse double layer of carbon nanotubes using classical theory: curvature effects on the Gouy-Chapman limit
द्वारा: Henstridge, M, और अन्य
प्रकाशित: (2010)

On the estimation of the diffuse double layer of carbon nanotubes using classical theory: Curvature effects on the Gouy-Chapman limit
द्वारा: Henstridge, M, और अन्य
प्रकाशित: (2010)

Anodic stripping voltammetry at hydrodynamic mercury thin film electrodes. Numerical simulation of stripping peaks for reversible processes at uniformly accessible electrodes
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A comparison of the Butler-Volmer and asymmetric Marcus-Hush models of electrode kinetics at the channel electrode
द्वारा: Henstridge, M, और अन्य
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Two-layer analytical model for estimation of layer thickness and flow using Diffuse Correlation Spectroscopy.
द्वारा: Jingyi Wu, और अन्य
प्रकाशित: (2022-01-01)

Voltammetric selectivity conferred by the modification of electrodes using conductive porous layers or films: The oxidation of dopamine on glassy carbon electrodes modified with multiwalled carbon nanotubes
द्वारा: Henstridge, M, और अन्य
प्रकाशित: (2010)

Asymmetric Marcus theory: Application to electrode kinetics
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प्रकाशित: (2012)

Electrode kinetics at carbon electrodes and the density of electronic states.
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प्रकाशित: (2012)

Mass transport to and within porous electrodes. Linear sweep voltammetry and the effects of pore size: The prediction of double peaks for a single electrode process
द्वारा: Henstridge, M, और अन्य
प्रकाशित: (2012)

The Marcus-Hush model of electrode kinetics at a single nanoparticle
द्वारा: Henstridge, M, और अन्य
प्रकाशित: (2014)

Dual microband electrodes: current distributions and diffusion layer 'titrations'. Implications for electroanalytical measurements
द्वारा: Svir, I, और अन्य
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Electrodes modified with electroinactive layers: distinguishing through-film transport from pinhole (pore) diffusion.
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प्रकाशित: (2009)

Catalytic mechanism in cyclic voltammetry at disc electrodes: an analytical solution.
द्वारा: Molina, A, और अन्य
प्रकाशित: (2011)

Analytical theory of the catalytic mechanism in square wave voltammetry at disc electrodes.
द्वारा: Molina, A, और अन्य
प्रकाशित: (2011)

Modelling electrode transients: The strongly implicit procedure
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प्रकाशित: (1996)

Tube electrode and electron spin resonance transient signals
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प्रकाशित: (1982)

Generator/Collector Experiments with a Single Electrode: Introduction and Application to Exploring the Oxidation Mechanism of Serotonin
द्वारा: Henstridge, M, और अन्य
प्रकाशित: (2009)

Nanoparticle modified electrodes can show an apparent increase in electrode kinetics due solely to altered surface geometry: The effective electrochemical rate constant for non-flat and non-uniform electrode surfaces
द्वारा: Ward, K, और अन्य
प्रकाशित: (2013)

Transient analysis of diffusion-induced deformation in a viscoelastic electrode
द्वारा: Yaohong Suo, और अन्य
प्रकाशित: (2019-06-01)

Studies in electrode kinetics
द्वारा: Henstridge, MC
प्रकाशित: (2013)

Rate Transient Behavior of Wells Intercepting Non-Uniform Fractures in a Layered Tight Gas Reservoir
द्वारा: Chengwei Zhang, और अन्य
प्रकाशित: (2022-08-01)

Thickness Uniformity Dependence on Polymer Viscosity in Silver-Nanowire-Embedded Flexible and Transparent Electrodes
द्वारा: Moonsoo Chae, और अन्य
प्रकाशित: (2020-03-01)

An Effect of Layered Auxiliary Cathode on Thickness Uniformity in Micro Electroforming Process
द्वारा: Huan Wang, और अन्य
प्रकाशित: (2023-06-01)

A comparison of Marcus-Hush vs. Butler-Volmer electrode kinetics using potential pulse voltammetric techniques
द्वारा: Laborda, E, और अन्य
प्रकाशित: (2011)

Coulostatic potential transients induced by laser heating of platinum stepped electrodes: influence of steps on the entropy of double layer formation
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प्रकाशित: (2004)

Theory of diffusion to an "annular microband" electrode
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प्रकाशित: (2009)

Comparative evaluation of the symmetric and asymmetric Marcus-Hush formalisms of electrode kinetics - The one-electron oxidation of tetraphenylethylene in dichloromethane on platinum microdisk electrodes
द्वारा: Suwatchara, D, और अन्य
प्रकाशित: (2012)