Ammonium-directed oxidation of cyclic allylic and homoallylic amines.

The ammonium-directed olefinic oxidation of a range of cyclic allylic and homoallylic amines has been investigated. Functionalization of a range of allylic 3-(N,N-dibenzylamino)cycloalk-1-enes with m-CPBA in the presence of Cl(3)CCO(2)H gives exclusively the corresponding syn-epoxide for the 5-membe...

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Main Authors: Bond, C, Cresswell, A, Davies, S, Fletcher, A, Kurosawa, W, Lee, J, Roberts, P, Russell, A, Smith, A, Thomson, J
格式: Journal article
語言:English
出版: 2009