Desymmetrization by direct cross-metathesis producing hitherto unreachable P-stereogenic phosphine oxides
Desymmetrization of prochiral di- and trialkenyl phosphine oxides by cross-metathesis with various olefinic partners allowed direct access to novel racemic P-stereogenic products featuring two or three different alkenyl groups. The excellent control of product selectivity and E/Z selectivity allowed...
| Main Authors: | , |
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| Format: | Journal article |
| Language: | English |
| Published: |
2005
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