Sr 2 MnO 2 Na 1.6 Se 2: A Metamagnetic Layered Oxychalcogenide Synthesized by Reductive Na Intercalation to Break [Se 2 ] 2– Perselenide Dimer Units

Recent advances in anion-redox topochemistry have enabled the synthesis of metastable mixed-anion solids. Synthesis of the new transition metal oxychalcogenide Sr2MnO2Na1.6Se2 by topochemical Na intercalation into Sr2MnO2Se2 is reported here. Na intercalation is enabled by the redox activity of [Se2...

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Bibliografske podrobnosti
Main Authors: Giri, S, Dey, S, Suard, E, Clarke, SJ
Format: Journal article
Jezik:English
Izdano: American Chemical Society 2024