Synthesis, Structure, and Ligand Exchange Reactions of Tetramethyleneethane Complexes of Cobalt
The synthesis of (η3:η3-TME)[Co(CO) 3]2 (1) was achieved using 2,3-bis(bromomethyl)-1,3- butadiene (TMEBr2) as the tetramethyleneethane (TME) ligand precursor and Na[Co(CO)4]. Solution NMR studies suggested an η3:η3-configuration, which has been confirmed in the solid state by single-crystal X-ray d...
| Main Authors: | , , , , , , |
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| Format: | Journal article |
| Language: | English |
| Published: |
2010
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