Solvent dependence of the g-anisotropy in the ESR of cyanide-bridged mixed-valence complexes.
The low temperature (approximately 5 K) X-band ESR spectra are reported of the cyanide-bridged mixed-valence complexes [(OC)5Cr(mu-CN)M(NH3)5]X2 (M = Ru, Os; X = PF6(-)) in frozen matrices formed from nitromethane, acetonitrile and dimethylformamide with toluene. The anisotropy (g paralell-g perpend...
| Main Authors: | , , , |
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| Format: | Journal article |
| Language: | English |
| Published: |
2008
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