Selective ethylene oligomerisation using supported tungsten mono-imido catalysts

A series of substituted phenyl mono-imido complexes of the type W(NR)Cl4(THF) (R = C6H5, 2,6-Me-C6H3, 3,5-Me-C6H3, 2,4,6 Me-C6H2, 4-OMe-C6H4, 2,6-F-C6H3 and 3,5 CF3-C6H3) have been synthesised and characterised. Reaction of these complexes with solid polymethylaluminoxane (sMAO) leads to immobilisat...

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Bibliographic Details
Main Authors: Wright, C, Williams, T, Turner, Z, Buffet, J, O'Hare, D
Format: Journal article
Published: Royal Society of Chemistry 2017