Photoswitchable stable charge-distributed states in a new cobalt complex exhibiting photo-induced valence tautomerism
We report the synthesis and magnetic and photomagnetic behaviour of a novel valence tautomeric cobalt complex, [Co(3,5-dbbq)2(μ-bpym)] (1) (3,5-dbbq = 3,5-di-tert-butyl-1,2-benzoquinone and μ-bpym = 2,2'-bipyrimidine). The synthesis is performed by reacting Co2(CO)8 and μ-bpym in the presence o...
Main Authors: | , , , , , |
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Format: | Journal article |
Language: | English |
Published: |
Royal Society of Chemistry
2015
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