Photoswitchable stable charge-distributed states in a new cobalt complex exhibiting photo-induced valence tautomerism

We report the synthesis and magnetic and photomagnetic behaviour of a novel valence tautomeric cobalt complex, [Co(3,5-dbbq)2(μ-bpym)] (1) (3,5-dbbq = 3,5-di-tert-butyl-1,2-benzoquinone and μ-bpym = 2,2'-bipyrimidine). The synthesis is performed by reacting Co2(CO)8 and μ-bpym in the presence o...

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Bibliographic Details
Main Authors: Slota, M, Blankenhorn, M, Heintze, E, Vu, M, Hübner, R, Bogani, L
Format: Journal article
Language:English
Published: Royal Society of Chemistry 2015