Photoswitchable stable charge-distributed states in a new cobalt complex exhibiting photo-induced valence tautomerism
We report the synthesis and magnetic and photomagnetic behaviour of a novel valence tautomeric cobalt complex, [Co(3,5-dbbq)2(μ-bpym)] (1) (3,5-dbbq = 3,5-di-tert-butyl-1,2-benzoquinone and μ-bpym = 2,2'-bipyrimidine). The synthesis is performed by reacting Co2(CO)8 and μ-bpym in the presence o...
Main Authors: | Slota, M, Blankenhorn, M, Heintze, E, Vu, M, Hübner, R, Bogani, L |
---|---|
Format: | Journal article |
Language: | English |
Published: |
Royal Society of Chemistry
2015
|
Similar Items
-
Putting the squeeze on valence tautomerism in cobalt-dioxolene complexes
by: Aston Summers, et al.
Published: (2024-10-01) -
Triggering of Valence Tautomeric Transitions in Dioxolene-Based Cobalt Complexes Influenced by Ligand Substituents, Co-ligands, and Anions
by: Sriram Sundaresan, et al.
Published: (2022-09-01) -
Valence Tautomerism in Chromium Half-Sandwich Triarylmethylium Dyads
by: Anja Rehse, et al.
Published: (2023-11-01) -
Photo-tautomerization of acetaldehyde to vinyl alcohol: a potential route to tropospheric acids.
by: Andrews, D, et al.
Published: (2012) -
Ultrafast Jahn‐Teller Photoswitching in Cobalt Single‐Ion Magnets
by: Sophie E. Canton, et al.
Published: (2023-07-01)