[Ru(bipy)(3)](2+) and [Os(bipy)(3)](2+) chromophores as sensitisers for near-infrared luminescence from Yb(iii) and Nd(iii) in d/f dyads: contributions from Forster, Dexter, and redox-based energy-transfer mechanisms.

The complexes and contain [M(bipy)(3)](2+) chromophores with a pendant aza-18-crown-6 macrocycle for binding of lanthanide(iii) ions. The photophysical properties of the adducts . and ., prepared by addition of excess Ln(NO(3))(3) (Ln = Nd, Yb) to solutions of and in MeCN, were examined using time-r...

Volledige beschrijving

Bibliografische gegevens
Hoofdauteurs: Lazarides, T, Tart, N, Sykes, D, Faulkner, S, Barbieri, A, Ward, MD
Formaat: Journal article
Taal:English
Gepubliceerd in: 2009