Correlating reactivity and selectivity to cyclopentadienyl ligand properties in Rh(III)-catalyzed C-H activation reactions: an experimental and computational study

Cp(X)Rh(III)-catalyzed C-H functionalization reactions are a proven method for the efficient assembly of small molecules. However, rationalization of the effects of cyclopentadienyl (Cp(X)) ligand structure on reaction rate and selectivity has been viewed as a black box, and a truly systematic study...

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Bibliographic Details
Main Authors: Piou, T, Romanov-Michailidis, F, Romanova-Michaelides, M, Jackson, K, Semakul, N, Taggart, T, Newell, B, Rithner, C, Paton, R, Rovis, T
Format: Journal article
Language:English
Published: American Chemical Society 2017