Adsorption and activation of molecular oxygen over atomic copper(I/II) site on ceria

Supported atomic metal sites have discrete molecular orbitals. Precise control over the energies of these sites is key to achieving novel reaction pathways with superior selectivity. Here, we achieve selective oxygen (O2) activation by utilising a framework of cerium (Ce) cations to reduce the energ...

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Bibliographic Details
Main Authors: Kang, L, Wang, B, Bing, Q, Zalibera, M, Büchel, R, Xu, R, Wang, Q, Liu, Y, Gianolio, D, Tang, CC, Gibson, EK, Danaie, M, Allen, C, Wu, K, Marlow, S, Sun, L-D, He, Q, Guan, S, Savitsky, A, Velasco-Vélez, JJ, Callison, J, Kay, CWM, Pratsinis, SE, Lubitz, W, Liu, J-Y, Wang, FR
Format: Journal article
Language:English
Published: Springer Nature 2020