Adsorption and activation of molecular oxygen over atomic copper(I/II) site on ceria

Supported atomic metal sites have discrete molecular orbitals. Precise control over the energies of these sites is key to achieving novel reaction pathways with superior selectivity. Here, we achieve selective oxygen (O2) activation by utilising a framework of cerium (Ce) cations to reduce the energ...

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Hlavní autoři: Kang, L, Wang, B, Bing, Q, Zalibera, M, Büchel, R, Xu, R, Wang, Q, Liu, Y, Gianolio, D, Tang, CC, Gibson, EK, Danaie, M, Allen, C, Wu, K, Marlow, S, Sun, L-D, He, Q, Guan, S, Savitsky, A, Velasco-Vélez, JJ, Callison, J, Kay, CWM, Pratsinis, SE, Lubitz, W, Liu, J-Y, Wang, FR
Médium: Journal article
Jazyk:English
Vydáno: Springer Nature 2020

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