Nucleophilic vinylic substitution in bicyclic methyleneaziridines: SNVπ or SNVσ?
A stereodefined monodeuterated methylene aziridine is shown to be prepared via coordinated reductive ring-opening of an alkynyl epoxide and diastereoselective tethered allene aziridination. Ring-opening of this aziridine with copper-based organometallics follows a pathway that results in stereoreten...
| المؤلفون الرئيسيون: | , , |
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| التنسيق: | Journal article |
| اللغة: | English |
| منشور في: |
Royal Society of Chemistry
2021
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