Contracted and expanded meso-alkynyl porphyrinoids: from triphyrin to hexaphyrin.

Contracted and expanded meso-alkynyl porphyrinoids: from triphyrin to hexaphyrin.

The boron trifluoride-catalyzed Rothemund condensation of triisopropylsilyl (TIPS) propynal 1 with 3,4-diethylpyrrole in dichloromethane, followed by oxidation with 2,3-dichloro-5,6-dicyano-1,4-benzoquinone (DDQ) generates a mixture of products, including [15]triphyrin(1.1.3) H3, corrole H(3)4, porp...

Полное описание

Библиографические подробности
Главные авторы:	Krivokapic, A, Cowley, A, Anderson, H
Формат:	Journal article
Язык:	English
Опубликовано:	2003

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