Reduction of carbon oxides by an acyclic silylene: reductive coupling of CO

Reactions of a boryl-substituted acyclic silylene with carbon dioxide and monoxide are reported. The former proceeds through oxygen atom abstraction, generating CO (with rearrangement of the putative silanone product through silyl-group transfer). The latter is characterized by reductive coupling of...

Full description

Bibliographic Details
Main Authors: Protchenko, A, Vasko, P, Do, D, Hicks, J, Fuentes, M, Jones, C, Aldridge, S
Format: Journal article
Language:English
Published: Wiley 2019