New titanium complexes containing an amidinate-imide supporting ligand set: Cyclopentadienyl, alkyl, borohydride, aryloxide, and amide derivatives

A range of chloride metathesis reactions of the monomeric titanium N,N′-bis(trimethylsilyl)-benzamidinato-imido complexes [Ti(NBut){(4-C6H4R)C(NSiMe3) 2}Cl(py)2] (R = H (1) or OMe (2)) are described. Thus, reaction of 1 or 2 with LiC5H5 gave the half-sandwich compounds [Ti(NBut){(4-C6H4R)C(NSiMe3) 2...

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Những tác giả chính: Stewart, P, Blake, A, Mountford, P
Định dạng: Journal article
Ngôn ngữ:English
Được phát hành: 1998