Hindered fluorescence quenching in an insulated molecular wire.

A [3]rotaxane 2 within 1(2) consisting of an anionic phenylene ethynylene dumbbell 2(4-) threaded through two cationic cyclophanes 1(2+) has been prepared using aqueous Glaser coupling. Stern-Volmer analysis of the fluorescence quenching using three different electron-acceptors (methyl viologen 13(2...

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Príomhchruthaitheoirí: Taylor, P, Hagan, A, Anderson, H
Formáid: Journal article
Teanga:English
Foilsithe / Cruthaithe: 2003