Evidence for concerted ring opening and C-Br bond breaking in UV-excited bromocyclopropane.
Photodissociation of gaseous bromocyclopropane via its A-band continuum has been studied at excitation wavelengths ranging from 230 nm to 267 nm. Velocity-map images of ground-state bromine atoms (Br), spin-orbit excited bromine atoms (Br*) and C3H5 hydrocarbon radicals reveal the kinetic energies o...
Main Authors: | Pandit, S, Preston, T, King, S, Vallance, C, Orr-Ewing, A |
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格式: | Journal article |
语言: | English |
出版: |
American Institute of Physics
2016
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