Rhodium-containing oxide-hydrides: covalently stabilized mixed-anion solids
<p>The first rhodium-containing oxide-hydride phases, LaSrCo<sub>0.5</sub>Rh<sub>0.5</sub>O<sub>3</sub>H and La<sub>0.5</sub>Sr<sub>1.5</sub>Mn<sub>0.5</sub>Rh<sub>0.5</sub>O<sub>3</sub>H, have been...
| Egile Nagusiak: | , |
|---|---|
| Formatua: | Journal article |
| Hizkuntza: | English |
| Argitaratua: |
Royal Society of Chemistry
2019
|
| Gaia: | <p>The first rhodium-containing oxide-hydride phases, LaSrCo<sub>0.5</sub>Rh<sub>0.5</sub>O<sub>3</sub>H and La<sub>0.5</sub>Sr<sub>1.5</sub>Mn<sub>0.5</sub>Rh<sub>0.5</sub>O<sub>3</sub>H, have been prepared <em>via</em> topochemical anion exchange. This clearly demonstrates the ability of rhodium, a late 4d transition metal, to kinetically stabilize oxide-hydride lattices, reinforcing the paradigm of covalent stabilization of transition-metal oxide-hydride phases.</p> |
|---|