Stereochemical aspects of nucleophilic addition reactions to alkoxycarbene cations of the iron chiral auxiliary [(eta(5)-C5H5)Fe(CO)(PPh3)]
Alkoxy carbene complexes incorporating the iron chiral auxiliary [(η5-C5H5)Fe(CO)(PPh3)] were prepared in good yields from either the corresponding acyl complexes or methoxymethyl complex of the auxiliary. A range of nucleophilic addition reactions to these alkoxy carbene complexes showed moderate t...
| Main Authors: | , , , |
|---|---|
| Format: | Journal article |
| Language: | English |
| Published: |
2013
|