Stereochemical aspects of nucleophilic addition reactions to alkoxycarbene cations of the iron chiral auxiliary [(eta(5)-C5H5)Fe(CO)(PPh3)]

Alkoxy carbene complexes incorporating the iron chiral auxiliary [(η5-C5H5)Fe(CO)(PPh3)] were prepared in good yields from either the corresponding acyl complexes or methoxymethyl complex of the auxiliary. A range of nucleophilic addition reactions to these alkoxy carbene complexes showed moderate t...

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Main Authors: Davies, S, Fletcher, A, Maberly, T, Thomson, J
格式: Journal article
語言:English
出版: 2013