Stereochemical aspects of nucleophilic addition reactions to alkoxycarbene cations of the iron chiral auxiliary [(eta(5)-C5H5)Fe(CO)(PPh3)]

Stereochemical aspects of nucleophilic addition reactions to alkoxycarbene cations of the iron chiral auxiliary [(eta(5)-C5H5)Fe(CO)(PPh3)]

Alkoxy carbene complexes incorporating the iron chiral auxiliary [(η5-C5H5)Fe(CO)(PPh3)] were prepared in good yields from either the corresponding acyl complexes or methoxymethyl complex of the auxiliary. A range of nucleophilic addition reactions to these alkoxy carbene complexes showed moderate t...

Disgrifiad llawn

Manylion Llyfryddiaeth
Prif Awduron:	Davies, S, Fletcher, A, Maberly, T, Thomson, J
Fformat:	Journal article
Iaith:	English
Cyhoeddwyd:	2013

Eitemau Tebyg

STEREOSELECTIVE ADDITIONS TO THE ALKOXYCARBENE CATIONS [ETA-5-C5H5)FE(CO)(PPH3)(=CHOME)], [ETA-5-C5H5)FE(CO)(PPH3)(=CETOME)]
gan: Baird, G, et al.
Cyhoeddwyd: (1984)

Stereoselective syntheses of substituted succinic acid derivatives of the iron chiral auxiliary [(eta(5)-C5H5)Fe(CO)(PPh3)]
gan: Bashiardes, G, et al.
Cyhoeddwyd: (2014)

ASYMMETRIC-SYNTHESIS VIA THE IRON CHIRAL AUXILIARY [(ETA-5-C5H5)FE(CO)(PPH3)]
gan: Davies, S
Cyhoeddwyd: (1988)

THE ASYMMETRIC SYNTHESIS OF (-)-ACTINONIN USING THE IRON CHIRAL AUXILIARY [(ETA5-C5H5)FE(CO)(PPH3)]
gan: Bashiardes, G, et al.
Cyhoeddwyd: (1988)

THE ASYMMETRIC-SYNTHESIS OF (-)-CAPTOPRIL UTILIZING THE IRON CHIRAL AUXILIARY [ETA-5-C5H5)FE(CO)(PPH3)]
gan: Bashiardes, G, et al.
Cyhoeddwyd: (1987)

ASYMMETRIC-SYNTHESIS OF HOMOCHIRAL BETA-LACTONES VIA THE IRON CHIRAL AUXILIARY [(ETA-5-C5H5)FE(CO)(PPH3)]
gan: Casegreen, S, et al.
Cyhoeddwyd: (1991)

SELF-RECOGNITION BY THE IRON CHIRAL AUXILIARY [(ETA-5-C5H5)FE(CO)(PPH3)] IN THE FORMATION OF (RR,SS)-[(ETA-5-C5H5)FE(CO)(PPH3)COCH2]2CH2
gan: Bodwell, G, et al.
Cyhoeddwyd: (1991)

ASYMMETRIC-SYNTHESIS OF 2,4-DISUBSTITUTED BUTYROLACTONES USING THE IRON CHIRAL AUXILIARY [ETA-5-C5H5)FE(CO)(PPH3)]
gan: Davies, S, et al.
Cyhoeddwyd: (1990)

ASYMMETRIC SYNTHESES OF ETHYL (S)-(+)-2-METHYLHEPT-4-YNOATE USING BOTH ENANTIOMERS OF THE CHIRAL IRON AUXILIARY [(ETA-5-C5H5)FE(CO)(PPH3)]
gan: Bodwell, G, et al.
Cyhoeddwyd: (1991)

SYNTHESIS OF ALPHA,BETA-UNSATURATED ACYL LIGANDS BOUND TO THE CHIRAL AUXILIARY [(ETA-5-C5H5)FE(CO)(PPH3)]
gan: Davies, S, et al.
Cyhoeddwyd: (1985)

FRAGMENTATION OF (ETA-5-C5H5)FE(CO)(PPH3)(COCH2COR) COMPLEXES TO THE CATION [(ETA-5-C5H5)FE(CO)2(PPH3)]+
gan: Davies, S, et al.
Cyhoeddwyd: (1983)

CHIRAL ORGANOMETALLIC NADH MIMICS - STEREOSELECTIVE REDUCTION OF ETHYL BENZOYLFORMATE UTILIZING THE HOMOCHIRAL AUXILIARY [(ETA-5-C5H5)FE(CO)(PPH3)]
gan: Davies, S, et al.
Cyhoeddwyd: (1990)

STEREOCHEMICAL CONTROL AND MECHANISTIC ASPECTS OF THE ALKYLATION OF [(ETA-5-C5H5)FE(PPH3,PPH2NET2)(CO)(COCH(ME)ET)]-LI+ - X-RAY CRYSTAL-STRUCTURE OF [(ETA-5-C5H5)FE(PPH3)(CO)(COCH(ME)ET)]
gan: Baird, G, et al.
Cyhoeddwyd: (1983)

STEREOSELECTIVE FORMATION OF 4-SUBSTITUTED-1,4-DIHYDRONICOTINOYL COMPLEXES UTILIZING THE CHIRAL AUXILIARY [(ETA-5-C5H5)FE(CO)(PPH3)]
gan: Beckett, R, et al.
Cyhoeddwyd: (1993)

Application of the chiral auxiliary [(eta(5)-C5H5)Fe(CO)(PPh(3))] to the stereoselective formation of 4-substituted-1,4-dihydronicotinoyl complexes
gan: Beckett, R, et al.
Cyhoeddwyd: (1996)

ELECTRON-RICH CATIONS - PREPARATION AND HYDRIDE REDUCTIONS OF THE CATIONS [FE(ETA-5-C5H5)(PHP(CH2CH2PPH2)2)]+, [FE(ETA-5-C5H5)(MEC(CH2PPH2)3)]+, AND [FE(ETA-5-C5H5)(C(CH2PPH2)4)]+
gan: Davies, S, et al.
Cyhoeddwyd: (1983)

OPENING OF CARBOHYDRATE 5,6-EPOXIDES WITH CHIRAL ACETATE AND PROPIONATE ENOLATE EQUIVALENTS ATTACHED TO THE IRON CHIRAL AUXILIARY [C5H5)FE(CO)(PPH(3))]
gan: Davies, S, et al.
Cyhoeddwyd: (1994)

SYNTHESIS AND STEREOSELECTIVE REACTIONS OF ALPHA,BETA-UNSATURATED ACYL LIGANDS BOUND TO THE CHIRAL AUXILIARY [(ETA(5)C5H5)FE(CO)(PPH3)] - A REVIEW
gan: Davies, S, et al.
Cyhoeddwyd: (1987)

ELECTRON-RICH CATIONS - PREPARATION AND HYDRIDE REDUCTIONS OF THE CATIONS ((ETA-5-C5H5)RU[MEC(CH2PPH2)3])+ AND "((ETA-5-C5H5)RU[PHP(CH2CH2PPH2)2])+
gan: Davies, S, et al.
Cyhoeddwyd: (1983)

STEREOSELECTIVE ALKYLATIONS OF ENOLATES DERIVED FROM LIGANDS ATTACHED TO THE INDENYL IRON CHIRAL AUXILIARY [ETA-5-C9H7)FE(CO)(PPH3)] - X-RAY CRYSTAL-STRUCTURE AND CONFORMATIONAL-ANALYSIS OF [ETA-5-C9H7)FE(CO)(PPH3)COCH3]
gan: Davies, S, et al.
Cyhoeddwyd: (1991)

A CONVENIENT SYNTHESIS OF [RU(ETA-C5H5)(PPH3)(CO)CL] AND THE CATIONS [RU(ETA-C5H5)(PPH3)L(CO)]+ [L = CO, PME3, OR P(OPH)3]
gan: Davies, S, et al.
Cyhoeddwyd: (1984)

CHIRAL ORGANOMETALLIC NADH MIMICS - STEREOSELECTIVE REDUCTION OF ETHYL BENZOYLFORMATE UTILIZING THE HOMOCHIRAL AUXILIARY [(ETA-5-C5H5)FE(CO)(PPH3)] AT C-3 AND A CHIRAL BETA-HYDROXY-CARBOXAMIDE DERIVED FROM VALINOL AT C-5
gan: Burgess, V, et al.
Cyhoeddwyd: (1990)

DISPROPORTIONATION OF THE IRON CARBONYL HYDRIDE "(ETA-5-C5H5)FE(CO)H(PH2PCH2CH2PPH2) TO THE IRON METHYL (ETA-5-C5H5)FE(PH2PCH2CH2PPH2)ME
gan: Davies, S, et al.
Cyhoeddwyd: (1982)

CONFORMATION ANALYSIS OF COMPOUNDS OF THE TYPE [FE(ETA-5-C5H5)(CO)(PPH3)(CH2ALKYL)], "[FE(ETA-5-C5H5)(CO)(PPH3)(CH2ARYL)] - REPLY
gan: Seeman, J, et al.
Cyhoeddwyd: (1985)

SYNTHESIS AND REACTIVITY OF THE PENTAMETHYLCYCLOPENTADIENYL IRON ACETYL COMPLE[(ETA(5)-C(5)ME(5))FE(CO)(PPH(3))COME]
gan: Barras, J, et al.
Cyhoeddwyd: (1993)

CONFORMATION-REACTIVITY RELATIONSHIPS FOR THE ORGANOTRANSITION-METAL COMPLEXES (ETA-5-C5H5)FE(CO)(PPH3)R AND (ETA-5-C5H5)RE(NO)(PPH3)R (R = ALKYL AND ARYL)
gan: Seeman, J, et al.
Cyhoeddwyd: (1985)

ASYMMETRIC-SYNTHESIS OF PHENYL ALKYL SULFOXIDES VIA THE NON-DESTRUCTIVE MEDIATION OF THE CHIRAL IRON ACYL[(ETA-5-C5H5)FE(CO)(PPH3)COCH2ME]
gan: Davies, S, et al.
Cyhoeddwyd: (1988)

RESOLUTION OF THE CHIRAL IRON ACETYL COMPLEX [(C5H5)FE(CO)(PPH3)COCH3]
gan: Baker, R, et al.
Cyhoeddwyd: (1993)

EVIDENCE FOR THE IRON FORMYL "(ETA-5-C5H5)FE(PH2PCH2CH2PPH2)(CHO)
gan: Davies, S, et al.
Cyhoeddwyd: (1982)

HYDRIDE REDUCTION OF THE CATION [(ETA-5-C5H5)FE(TRIPHOS)]PF6 - DIRECT NUCLEOPHILIC-ATTACK ON THE METAL, AND HYDROGEN-EXCHANGE IN THE PRODUCT HYDRIDE (ETA-5-C5H5)FEH(TRIPHOS), (TRIPHOS=PH2PCH2CH2PPHCH2CH2PPH2)
gan: Davies, S, et al.
Cyhoeddwyd: (1980)

KINETIC RESOLUTION OF THE CHIRAL IRON ACETYL [FE(MU(5)-C5H5)(CO)(PPH3)COME]
gan: Casegreen, S, et al.
Cyhoeddwyd: (1993)

BIMETALLIC CYANO-BRIDGED CATIONS - PREPARATION AND HYDRIDE REDUCTION OF [(ETA-5-C5H5)L2RU(MU-CN)ML'2(ETA-5-C5H5)]PF6[L2,L'2=(PPH3)2,PH2PCH2CH2PPH2 - M = RU OR FE] - FORMATION OF [RU(ETA-5-C5H5)(PPH3)H3] AND X-RAY CRYSTAL-STRUCTURE OF [(ETA-5-C5H5)(PH2PCH2CH2PPH2)RU(MU-CN)RU(PPH3)2(ETA-5-C5H5)]PF6
gan: Baird, G, et al.
Cyhoeddwyd: (1985)

THE STEREOSELECTIVE NUCLEOPHILIC-ADDITION OF CYANIDE TO THE CATIONIC RUTHENIUM COMPLEXES [(ETA-5-C5H5)L2RU=C=C(ME)PH]+ (L2 = (PME3)2 OR (PPH2CH2)2)
gan: Davies, S, et al.
Cyhoeddwyd: (1991)

HYDRIDE REDUCTION OF THE CATION [ETA-5-C5H5)FE(PH2PCH2CH2PPH2)CO]PF6 - FORMATION OF "(ETA-5-C5H5)FEH(CO)(PH2PCH2CH2PPH2) AND ELIMINATION OF H-2 FROM [(ETA-5-C5H5)FEH(CO)]2(PH2PCH2CH2PPH2)
gan: Davies, S, et al.
Cyhoeddwyd: (1982)

HYDRIDE REDUCTION OF THE CATION [(ETA-5-C5H5)FE(PH2PCH2CH2PPH2)CO]PF6 - FORMATION OF "(ETA-5-C5H5)FEH(CO)(PH2PCH2CH2PPH2) AND ELIMINATION OF H-2 FROM [(ETA-5-C5H5)FEH(CO)]2(PH2PCH2CH2PPH2)
gan: Davies, S, et al.
Cyhoeddwyd: (1983)

HYDRIDE ADDITION TO THE CATIONS [( ETA-5-C5H5)RU(L)2CO]+ (L=PPH3, L2=PH2PCH2CH2PPH2)
gan: Davies, S, et al.
Cyhoeddwyd: (1984)

CHIRAL DIENOLATES - FORMATION AND STEREOSELECTIVE ALPHA-ALKYLATION OF THE LITHIUM DIENOLATE DERIVED FROM (Z)-[(ETA-5-C5H5)FE(CO)(PPH3)COCH=CHME] - X-RAY CRYSTAL-STRUCTURE OF (RS)-(Z)-[(ETA-5-C5H5)FE(CO)(PPH3)COCH=CHME]
gan: Davies, S, et al.
Cyhoeddwyd: (1987)

ASYMMETRIC DIELS-ALDER REACTIONS - (S)-(+)-[(ETA-5-C5H5)FE(CO)(PPH3)COCH=CH2] AS A CHIRAL ACRYLATE DIENOPHILE EQUIVALENT
gan: Davies, S, et al.
Cyhoeddwyd: (1986)

STEREOSELECTIVE SYNTHESIS OF (3R,4S)-STATINE UTILIZING THE IRON ACETYL COMPLEX [(ETA-5-C5H5)FE(CO)(PPH3)COME] AS A CHIRAL ACETATE ENOLATE EQUIVALENT
gan: Cooke, J, et al.
Cyhoeddwyd: (1993)

STEREOSPECIFICITY OF THE REARRANGEMENT OF THE ALPHA-ALKOXY IRON ACYL [(ETA-5-C5H5)FE(CO)(PPH3)COCH2OCH2PH] TO THE ALPHA-METALLA-ESTER [(ETA-5-C5H5)FE(CO)(PPH3)CH2CO2CH2PH]
gan: Davies, S, et al.
Cyhoeddwyd: (1987)