Deltahedral germanium clusters: insertion of transition-metal atoms and addition of organometallic fragments.

Deltahedral germanium clusters: insertion of transition-metal atoms and addition of organometallic fragments.

Reactions of nine-atom deltahedral clusters of germanium with Ni(COD)2 and/or Ni(PPh3)2(CO)2 in ethylenediamine yielded the Ni-centered heteroatomic 10-atom clusters [Ni@(Ge9Ni-CO)]2- and [Ni@(Ge9Ni-en)]3-, as well as the empty 10-atom heteroatomic cluster [Ge9Ni-CO]3-. A ligand exchange reaction be...

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Dettagli Bibliografici
Autori principali:	Goicoechea, J, Sevov, S
Natura:	Journal article
Lingua:	English
Pubblicazione:	2006

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