Chromium(II)-mediated synthesis of vinylbis(silanes) from aldehydes and a study of acid- and base-induced reactions of the derived epoxybis(silanes): a synthesis of acylsilanes
The synthesis of vinylbis(silanes) 1 from aldehydes and dibromomethylenebis(trimethylsilane) using chromium(II) chloride in DMF is described. Epoxidation of vinylbis(silanes) 1 and treatment of the resulting epoxybis(silanes) 2 with sulfuric acid in methanol gives acylsilanes 3. Mechanistic studies...
| Main Authors: | , , |
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| Format: | Journal article |
| Language: | English |
| Published: |
1997
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