Infrared spectroscopy during electrocatalytic turnover reveals the Ni-L active site state during H2 oxidation by a NiFe hydrogenase.

Infrared spectroscopy during electrocatalytic turnover reveals the Ni-L active site state during H2 oxidation by a NiFe hydrogenase.

We demonstrate a novel in situ infrared spectroscopic approach for the characterization of hydrogenase during catalytic turnover. E. coli hydrogenase 1 (Hyd-1) is adsorbed on a high surface-area carbon electrode and subjected to the same electrochemical control and efficient supply of substrate as i...

Полное описание

Библиографические подробности
Главные авторы:	Ash, P, Healy, A, Vincent, K, Hidalgo Gonzalez, R
Формат:	Journal article
Язык:	English
Опубликовано:	Wiley 2015

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