Mechanisms of IR amplification in radical cation polarons

Break down of the Born–Oppenheimer approximation is caused by mixing of electronic and vibrational transitions in the radical cations of some conjugated polymers, resulting in unusually intense vibrational bands known as infrared active vibrations (IRAVs). Here, we investigate the mechanism of this...

Бүрэн тодорхойлолт

Номзүйн дэлгэрэнгүй
Үндсэн зохиолчид: William, JK, Jirásek, M, Peeks, MD, Greetham, GM, Sazanovich, IV, Donaldson, PM, Towrie, M, Parker, AW, Anderson, HL
Формат: Journal article
Хэл сонгох:English
Хэвлэсэн: Royal Society of Chemistry 2020