Mechanisms of IR amplification in radical cation polarons

Break down of the Born–Oppenheimer approximation is caused by mixing of electronic and vibrational transitions in the radical cations of some conjugated polymers, resulting in unusually intense vibrational bands known as infrared active vibrations (IRAVs). Here, we investigate the mechanism of this...

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書誌詳細
主要な著者: William, JK, Jirásek, M, Peeks, MD, Greetham, GM, Sazanovich, IV, Donaldson, PM, Towrie, M, Parker, AW, Anderson, HL
フォーマット: Journal article
言語:English
出版事項: Royal Society of Chemistry 2020