Ion pairing in ionic liquids controls the Corannulene reduction mechanism

The electroreduction of corannulene (C20H10) has been investigated in a Room Temperature Ionic Liquid (RTIL) for the first time. In the RTIL 1-butyl-1-methylpyrrolidinium bis(trifluoromethanesulfonyl)imide ([Bmpyrr][NTf2]) the resultant voltammetry shows a peak-to-peak separation of 100 mV, and this...

Full description

Bibliographic Details
Main Authors: Tanner, E, Compton, R, Batchelor-McAuley, C, Foong, K, Hossain, M, Aldous, L
Format: Journal article
Published: American Chemical Society 2016