Temperature dependence of OH yield, translational energy, and vibrational branching in the reaction of O(3P)(g) with liquid squalane

The relative reactivity of the liquid surface of a long-chain, partially branched hydrocarbon (squalane, C30H62) with gas-phase O(3P) atoms has been measured as a function of liquid temperature. The O(3P) atoms were generated with a superthermal velocity distribution by 355 nm photolysis of NO2. Las...

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Bibliographic Details
Main Authors: Allan, M, Bagot, P, Costen, M, McKendrick, K
Format: Journal article
Language:English
Published: 2007