Chemo- and regioselective synthesis of acyl-cyclohexenes by a tandem acceptorless dehydrogenation-[1,5]-hydride shift cascade

An atom-economical methodology to access substituted acyl-cyclohexenes from pentamethylacetophenone and 1,5-diols is described. This process is catalyzed by an iridium(I) catalyst in conjunction with a bulky electron rich phosphine ligand (CataCXium A) which favors acceptorless dehydrogenation over...

সম্পূর্ণ বিবরণ

গ্রন্থ-পঞ্জীর বিবরন
প্রধান লেখক: Smith, L, Armstrong, R, Matheau-Raven, D, Donohoe, T
বিন্যাস: Journal article
ভাষা:English
প্রকাশিত: American Chemical Society 2020