Chemo- and regioselective synthesis of acyl-cyclohexenes by a tandem acceptorless dehydrogenation-[1,5]-hydride shift cascade

Chemo- and regioselective synthesis of acyl-cyclohexenes by a tandem acceptorless dehydrogenation-[1,5]-hydride shift cascade

An atom-economical methodology to access substituted acyl-cyclohexenes from pentamethylacetophenone and 1,5-diols is described. This process is catalyzed by an iridium(I) catalyst in conjunction with a bulky electron rich phosphine ligand (CataCXium A) which favors acceptorless dehydrogenation over...

書目詳細資料
Main Authors:	Smith, L, Armstrong, R, Matheau-Raven, D, Donohoe, T
格式:	Journal article
語言:	English
出版:	American Chemical Society 2020

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