Simple phosphinate ligands access zinc clusters identified in the synthesis of zinc oxide nanoparticles

The bottom-up synthesis of ligand-stabilized functional nanoparticles from molecular precursors is widely applied but is difficult to study mechanistically. Here we use 31 P NMR spectroscopy to follow the trajectory of phosphinate ligands during the synthesis of a range of ligated zinc oxo clusters,...

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Main Authors: Pike, S, White, E, Shaffer, M, Williams, C
格式: Journal article
语言:English
出版: Nature Publishing Group 2016