Impedance voltammetry of electro-dimerization mechanisms: Application to the reduction of the methyl viologen di-cation at mercury electrodes and aqueous solutions

The faradaic impedance for an electrode mechanism with a reversible homogeneous dimerization reaction following the electron transfer step is derived. The chemical reaction shows up in the frequency dependence of the faradaic impedance and admittance in a similar way as deduced by Sluyters-Rehbach a...

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Detalles Bibliográficos
Main Authors: Rueda, M, Compton, R, Alden, J, Prieto, F
Formato: Journal article
Idioma:English
Publicado: 1998