Studies on the reactivity of group 15 Zintl ions with carbodiimides: synthesis and characterization of a heptaphosphaguanidine dianion.
Reaction of the hydrogenheptaphosphide dianion, [HP(7)](2-), with one equivalent of bis(2,6-diisopropylphenyl)carbodiimide yielded the exo-functionalized cluster [P(7)C(NDipp)(NHDipp)](2-) (Dipp = 2,6-diisopropylphenyl). This species was characterized by single crystal X-ray diffraction, multielemen...
| Main Authors: | , |
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| Format: | Journal article |
| Language: | English |
| Published: |
2012
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