Porphyrin dimer carbocations with strong near infrared absorption and third-order optical nonlinearity.

Colored carbocations beyond the visible! A porphyrin dimer carbocation is synthesized with effective delocalization over 18 conjugated bonds. Placing a carbocation at the center of a conjugated porphyrin dimer shifts its absorption into the infrared and results in strong ultrafast nonlinear optical...

Полное описание

Библиографические подробности
Главные авторы: Thorley, K, Hales, J, Anderson, H, Perry, J
Формат: Journal article
Язык:English
Опубликовано: 2008