Multiple metal-bound oligomers from Ir-catalysed dehydropolymerisation of H3B center dot NH3 as probed by experiment and computation
Multiple metal-bound oligomers in the dehydropolymerisation of H 3B·NH3 have been observed by electrospray- ionisation mass spectrometry and NMR spectroscopy using the catalytic metal fragment {Ir(PCy3)2(H)2}+. A computational study suggests that sterics dictate whether multiple dehydrogenation/B-N...
| Main Authors: | , , , , , |
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| Format: | Journal article |
| Language: | English |
| Published: |
Royal Society of Chemistry
2014
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