Synthesis and C-alkylation of hindered aldehyde enamines.
A new reactivity mode of hindered lithium amides with terminal epoxides is described whereby aldehyde enamines are produced via a previously unrecognized reaction pathway. Some of these aldehyde enamines display unprecedented C-alkylation reactivity toward unactivated primary and secondary alkyl hal...
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Detalhes bibliográficos
| Main Authors: |
Hodgson, D,
Bray, C,
Kindon, N,
Reynolds, N,
Coote, S,
Um, J,
Houk, K |
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| Formato: | Journal article
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| Idioma: | English |
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| Publicado em: |
2009
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