Carbon dioxide binding to metal oxides: Infrared spectroscopy of NbO2+(CO2)n and TaO2+(CO2)n complexes

We report the results of an infrared photodissociation spectroscopy study to determine the structures of gas–phase NbO2(CO2)n+ and TaO2(CO2)n+ (n = 1–7) ion–molecule complexes. The experimental spectra, recorded in the region of the CO2 asymmetric stretch using the inert messenger technique, are int...

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Main Authors: Iskra, A, Gentleman, A, Cunningham, E, Mackenzie, S
格式: Journal article
出版: Elsevier 2018