A monoanionic arsenide source: Decarbonylation of the 2-arsaethynolate anion upon reaction with bulky stannylenes.

We report fundamental studies on the reactivity of the 2-arsaethynolate anion (AsCO(-) ), a species that has only recently become synthetically accessible. The reaction of AsCO(-) with the bulky stannylene Ter2 Sn (Ter=2,6-bis[2,4,6-trimethylphenyl]phenyl) is described, which leads to the unexpected...

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Bibliographic Details
Main Authors: Hinz, A, Goicoechea, J
Format: Journal article
Language:English
Published: Wiley 2016