Reactivity studies of [Co@Sn9]4- with transition metal reagents: bottom-up synthesis of ternary functionalized zintl clusters
The binary cluster [Co@Sn9]4– (1) was extracted directly from ethylenediamine (en) solutions of an intermetallic precursor with nominal composition “K5Co3Sn9”, and its reactions with various organometallic reagents were explored. Reaction with Ni(PPh3)2(CO)2 gives [Co@Sn9Ni(CO)]3– (2), a Co-centered...
| Main Authors: | , , , , |
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| Format: | Journal article |
| Language: | English |
| Published: |
American Chemical Society
2018
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