Imido titanium compounds bearing the 6-dimethylamino-1,4,6-trimethyl-1,4-diazacycloheptane ligand: synthesis, structures, solution dynamics and ethylene polymerisation capability.
Reaction of Me(4)DACH (6-dimethylamino-1,4,6-trimethyl-1,4-diazacycloheptane) with Ti(N(t)Bu)Cl(2)(py)(3) or Ti(N(t)Bu)Cl(2)(NHMe(2))(2) gave Ti(N(t)Bu)(Me(4)DACH)Cl(2) (1) which in CD(2)Cl(2) solution exists as a mixture of trans and cis isomers (defined with respect to the imido ligand and the exo...
| Main Authors: | , , , |
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| Format: | Journal article |
| Language: | English |
| Published: |
2008
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