C–H and H–H activation at a di-titanium centre
The reaction of the bis(pentalene)dititanium complex Ti2(μ:η5,η5-Pn†)2 (Pn† = C8H4(1,4-SiiPr3)2) with the N-heterocyclic carbene 1,3,4,5-tetramethylimidazol-2-ylidene results in intramolecular C-H activation of one of the iPr methyl groups of a Pn† ligand and formation of a "tucked-in" bri...
Main Authors: | , , |
---|---|
Formato: | Journal article |
Idioma: | English |
Publicado: |
Royal Society of Chemistry
2017
|