C–H and H–H activation at a di-titanium centre

The reaction of the bis(pentalene)dititanium complex Ti2(μ:η5,η5-Pn†)2 (Pn† = C8H4(1,4-SiiPr3)2) with the N-heterocyclic carbene 1,3,4,5-tetramethylimidazol-2-ylidene results in intramolecular C-H activation of one of the iPr methyl groups of a Pn† ligand and formation of a "tucked-in" bri...

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Detalles Bibliográficos
Main Authors: Tsoureas, N, Green, J, Cloke, F
Formato: Journal article
Idioma:English
Publicado: Royal Society of Chemistry 2017