Bifunctional iminophosphorane organocatalysts for enantioselective synthesis: application to the ketimine nitro-Mannich reaction.

The design, synthesis, and development of a new class of modular, strongly basic, and tunable bifunctional Brønsted base/H-bond-donor organocatalysts are reported. These catalysts incorporate a triaryliminophosphorane as the Brønsted basic moiety and are readily synthesized via a last step Staudinge...

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Detalhes bibliográficos
Main Authors: Núñez, MG, Farley, A, Dixon, D
Formato: Journal article
Idioma:English
Publicado em: 2013