Reversible [4 + 1] Cycloaddition of Arenes by a “Naked” Acyclic Aluminyl Compound
The large steric profile of the N-heterocyclic boryloxy ligand, –OB(NDippCH)2, and its ability to stabilize the metal-centered HOMO, are exploited in the synthesis of the first example of a “naked” acyclic aluminyl complex, [K(2.2.2-crypt)][Al{OB(NDippCH)2}2]. This system, which is formed by su...
| Main Authors: | , , , , , , , |
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| Format: | Journal article |
| Language: | English |
| Published: |
American Chemical Society
2024
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