High yield protection of alcohols, including tertiary and base sensitive alcohols, as benzhydryl ethers by heating with diphenyldiazomethane in the absence of any other reagent

A protecting group that can be introduced efficiently without the need for any acid or base catalysis and which is not prone to acid or base catalysed migration is a significant advantage for many syntheses. Benzhydryl [diphenylmethyl] ethers of sugar lactones are formed in high yield under neutral...

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Váldodahkkit: Best, D, Jenkinson, S, Rule, S, Higham, R, Mercer, T, Newell, R, Weymouth-Wilson, A, Fleet, G, Petursson, S
Materiálatiipa: Journal article
Giella:English
Almmustuhtton: 2008