Mn(I) in an extended oxide: the synthesis and characterization of La(1-x)Ca(x)MnO(2+δ) (0.6 ≤ x ≤ 1).

Reduction of La(1-x)Ca(x)MnO(3) (0.6 ≤ x ≤ 1) perovskite phases with sodium hydride yields materials of composition La(1-x)Ca(x)MnO(2+δ). The calcium-rich phases (x = 0.9, 1) adopt (La(0.9)Ca(0.1))(0.5)Mn(0.5)O disordered rocksalt structures. However local structure analysis using reverse Monte Carl...

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Bibliografische gegevens
Hoofdauteurs: Dixon, E, Hadermann, J, Ramos, S, Goodwin, A, Hayward, M
Formaat: Journal article
Taal:English
Gepubliceerd in: 2011