Mn(I) in an extended oxide: the synthesis and characterization of La(1-x)Ca(x)MnO(2+δ) (0.6 ≤ x ≤ 1).
Reduction of La(1-x)Ca(x)MnO(3) (0.6 ≤ x ≤ 1) perovskite phases with sodium hydride yields materials of composition La(1-x)Ca(x)MnO(2+δ). The calcium-rich phases (x = 0.9, 1) adopt (La(0.9)Ca(0.1))(0.5)Mn(0.5)O disordered rocksalt structures. However local structure analysis using reverse Monte Carl...
Hoofdauteurs: | , , , , |
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Formaat: | Journal article |
Taal: | English |
Gepubliceerd in: |
2011
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